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E242 / Preservatives

Dimethyl dicarbonate

Selected sources checked · Scope & sources

Safety in brief

Safe

Recorded EatMatrix rating, not a new clinical review. The amount, your sensitivities and country rules still matter.

Watch for
No allergen or sensitivity is recorded for this ingredient here. Check the whole product label; this is not an allergen-free guarantee.
Our advice
Read the whole food label and consider how often you eat the product. A name or E number does not tell you the amount, and an ingredient rating cannot assess the entire food.
What it is

Dimethyl dicarbonate (DMDC) is a preservative added to wine, fruit juices, and some non-alcoholic beverages to kill yeast and prevent fermentation or spoilage during bottling. Its key advantage is that it breaks down completely within a few hours into carbon dioxide and trace amounts of methanol, leaving no active residue in the final product. It's approved as safe by the FDA and EFSA for use within strict dosing limits, and because it fully decomposes, it doesn't need to be declared as an ingredient on final product labels in most jurisdictions.

Also appears on labels as: Dimethyl dicarbonate, DMDC, E242, E 242, E-242, INS 242, Additive E242, Dimethyl pyrocarbonate, Dimethyl carbonate dicarbonate, DMDC preservative, Carbonic acid dimethyl ester, C4H6O5.

Dietary information

Vegan
Yes
Halal
Yes
Gluten-free
Yes
Allergens
None recorded

Recorded ingredient information. Check the product label or certification: sources, other ingredients and cross-contact can vary.

Research & body effects

Health notes from our ingredient record

  • Must be handled and dosed carefully by manufacturers before bottling; direct consumer exposure to the undiluted compound does not occur since it fully decomposes before the product reaches consumers.
  • Generally recognized as safe at approved use levels; trace methanol formed during breakdown is well within naturally occurring dietary levels.

Other references from our ingredient record

These links come from the original ingredient record. They are separate from the source reviews above and have not all been checked for the exact ingredient, amount consumed or claim. Dates are shown newest first.

  1. Scientific opinion on the re‐evaluation of dimethyl dicarbonate (DMDC, E 242) as a food additive — EFSA Panel on Food Additives, EFSA Journal (2015). Official EFSA scientific opinion (bibliographic reference, imported 2026-10-13). It covers the additive as a group assessment and is not an individual human study; read the opinion for its findings.
Country rules

Country checks for E242

Permission depends on the market, type of food, amount and conditions. A scientific opinion or an E-number alone does not establish a legal use. These checks are separate from the stored EatMatrix rating.

Compare all eight markets and their sources
MarketWhat is checked
European Union

Regulation (EC) 1333/2008, Annex II Part B, version , contains the exact code E242: Dimethyl dicarbonate.

Listing alone does not allow every food use. Part E food categories, limits, specifications and applicable later acts still need a product-specific check. Source read: .

Great Britain

The FSA register record for E242 (Dimethyl dicarbonate) lists “Authorised” in England, Scotland and Wales.

Register updated: 01 April 2025; record checked: . Food-specific conditions and specifications still need a separate legal check.

United States

Selected US conditions for Dimethyl dicarbonate

Official federal text current through ; read .

Food uses, limits and exceptions

Selected beverage uses

The section covers microbial control during final packaging after the viable microbial load has been reduced to at most 500 microorganisms/mL. It specifies at most 200 ppm for wine, dealcoholised wine and low-alcohol wine; and at most 250 ppm for ready-to-drink teas and two narrowly defined beverage groups.

21 CFR 172.133

The beverage definitions matter

The other groups are carbonated or noncarbonated beverages with at most 1% juice and specified added sodium and potassium electrolyte concentrations; and carbonated dilute beverages with juice, fruit flavour or both, with at most 50% juice. The electrolyte ranges, additive purity, impurity limits and use directions in the source still apply. A 250 ppm limit is not permission for every drink.

21 CFR 172.133

EatMatrix’s reading: a legal use condition answers where and how an ingredient may be used. It is not a test of your product, a personal safe intake or a claim that the ingredient benefits your body. Match the named substance, food and amount. Other federal provisions, food standards, state rules and later changes may also apply; this is a selected source review, not a complete product-compliance decision.

Northern Ireland

Review pending. Check the applicable EU rules and territory arrangements; the GB register alone does not establish this status. FSA guidance is a starting source, not a verified permission for this entry.

Canada

Named food-use records located. Health Canada lists the preparations below for specified foods and purposes. This is conditional permission for those uses, not approval of every product or a personal safety verdict.

Only the named records and conditions below were located. Exact composition and specifications still need matching.

Source tables captured . List publication dates are shown separately. Good Manufacturing Practice (GMP) is a condition of use, not an unlimited amount or a recommended intake.

Food and Drug Regulations B.16.003 requires the listed source, purpose, amount and other conditions to match. The official consolidation read was current to 21 September 2026; product specifications and applicable later changes still need checking.

Read 3 listed food-use conditions

Dimethyl Dicarbonate

Health Canada: List of Permitted Preservatives. List published ; item D.1.

  • Food: (a) Cider; Fruit wine; Perry; Unstandardized alcoholic ciders

    Purpose: (a) Preservative

    Limit and conditions: (a) 250 ppm

    Source modification reference: NOM/ADM-0009 (see the official list).

  • Food: (b) Unstandardized water-based non-alcoholic beverages

    Purpose: (b) Preservative

    Limit and conditions: (b) 250 ppm

    Source modification reference: NOM/ADM-0170 (see the official list).

  • Food: (c) Wine

    Purpose: (c) Preservative

    Limit and conditions: (c) 200 ppm

    Source modification reference: NOM/ADM-0009 (see the official list).

EatMatrix reading: match the exact preparation and food first. A manufacturing limit is not an acceptable daily intake (ADI). A label without the amount cannot establish exposure, and an unlisted name here does not establish a ban.

Australia

Review pending. Food Standards Code permissions and conditions need an additive-specific check. FSANZ food-additive rules is a starting source, not a verified permission for this entry.

New Zealand

Review pending. Food Standards Code permissions and conditions need an additive-specific check. FSANZ food-additive rules is a starting source, not a verified permission for this entry.

Japan

Review pending. The relevant list, identity and use standards need an additive-specific check. CAA food-additive lists is a starting source, not a verified permission for this entry.

Sources & review status

Check what each source covers: an authority’s conclusion, a research finding and a country’s legal permission answer different questions.

What this guide covers

Official assessment sources
Commission-listed EFSA references for E242. Bibliographic identity checked; latest findings and current use rules need separate review.
Original ingredient record
1 research link; newest recorded date: . Sources added separately to this guide are not included in this count.

This guide brings together our ingredient record and the dated sources shown here. Missing information describes a gap in this guide; it does not mean an ingredient is untested, safe or harmful. This is not a complete review of every study, preparation or current country rule. The amount in a product and how it is used still matter.

How to read the ratings, research and country checks
Agency labels recorded by EatMatrix

These are imported database classifications, not verified current statements from each authority. Use the dated official sources below for their actual scope and conclusions.

AuthorityDatabase label
FDASafe
WHOSafe
EFSASafe
FSANZSafe
JapanSafe
UK FSASafe
Health CanadaSafe

Official assessment sources for E242

The European Commission’s re-evaluation table lists official EFSA documents for this additive. Their identifiers and subjects were checked against publisher bibliographic records. A missing research link in the EatMatrix database does not mean the additive has never been assessed.

Name in the Commission table: Dimethyl dicarbonate.

These are assessment references, including historical or group assessments. They do not establish the latest scientific conclusion, a human health benefit or risk, or current permission to use the additive in a particular food. Later assessments, corrections and food-use conditions need separate review. The recorded EatMatrix rating above is unchanged.

European Commission re-evaluation table, status as of . EatMatrix checked this bibliography on .

Database updated: . What does an E number mean on a food label?

Common questions

Frequently asked questions

What is EatMatrix's recorded rating for E242?

The recorded EatMatrix rating for E242 (Dimethyl dicarbonate) is “Safe”. It is calculated from labels stored in our ingredient database. These labels are not verified current regulator decisions or country permissions. A database update date is not a scientific review date.

Is E242 vegan, halal or gluten-free?

According to our ingredient data for Dimethyl dicarbonate — vegan: yes, vegetarian: yes, halal: yes, kosher: yes, gluten-free: yes, dairy-free: yes. Manufacturing sources can vary between products; check the label if it matters to you.

What is E242 and why is it used?

Dimethyl dicarbonate (DMDC) is a preservative added to wine, fruit juices, and some non-alcoholic beverages to kill yeast and prevent fermentation or spoilage during bottling. Its key advantage is that it breaks down completely within a few hours into carbon dioxide and trace amounts of methanol, leaving no active residue in the final product. It's approved as safe by the FDA and EFSA for use within strict dosing limits, and because it fully decomposes, it doesn't need to be declared as an ingredient on final product labels in most jurisdictions.

Does E242 contain allergens?

No known allergens are recorded for Dimethyl dicarbonate.

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This page shows information and classifications recorded in our ingredient database. Current scientific and market-specific verification remains pending as described above. It is general information, not medical advice.