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E302 / Antioxidants & acidity regulators

Calcium ascorbate

Selected sources checked · Scope & sources

Safety in brief

Safe

Recorded EatMatrix rating, not a new clinical review. The amount, your sensitivities and country rules still matter.

Watch for
No allergen or sensitivity is recorded for this ingredient here. Check the whole product label; this is not an allergen-free guarantee.
Our advice
Read the whole food label and consider how often you eat the product. A name or E number does not tell you the amount, and an ingredient rating cannot assess the entire food.
What it is

Calcium ascorbate (E302) is a buffered, less acidic form of vitamin C made by combining ascorbic acid with calcium. It is used in food as an antioxidant to preserve color and flavor, and as a dietary supplement that is gentler on the stomach than plain vitamin C while also contributing a small amount of calcium. It supports the same immune and antioxidant functions as other forms of vitamin C.

Also appears on labels as: Calcium ascorbate, Ascorbic acid calcium salt, Vitamin C calcium salt, Ca ascorbate, Food grade calcium ascorbate, E302, E 302, E-302, INS 302, Calcium L-ascorbate, Additivo alimentare E302, Additif alimentaire E302.

Dietary information

Vegan
Yes
Halal
Yes
Gluten-free
Yes
Allergens
None recorded

Recorded ingredient information. Check the product label or certification: sources, other ingredients and cross-contact can vary.

Research & body effects

Selected research on E302

How to read study types
  1. Regulator reviewEFSA re-evaluation of ascorbic acid and its sodium and calcium salts

    No safety concern at reported uses and no need for a numerical daily limit. Long-term animal studies showed no harm, even at high doses.

Summaries of each source's published abstract or statement, checked . This is a selection of sources, not a complete literature review. Authority assessments apply to the uses and places they cover.

Health notes from our ingredient record

  • Generally recognized as safe at typical food and supplement levels.

Other references from our ingredient record

These links come from the original ingredient record. They are separate from the source reviews above and have not all been checked for the exact ingredient, amount consumed or claim. Dates are shown newest first.

  1. Scientific Opinion on the re‐evaluation of ascorbic acid (E 300), sodium ascorbate (E 301) and calcium ascorbate (E 302) as food additives — EFSA Panel on Food Additives, EFSA Journal (2015). Official EFSA scientific opinion (bibliographic reference, imported 2026-10-13). It covers the additive as a group assessment and is not an individual human study; read the opinion for its findings.
Country rules

Country checks for E302

Permission depends on the market, type of food, amount and conditions. A scientific opinion or an E-number alone does not establish a legal use. These checks are separate from the stored EatMatrix rating.

Compare all eight markets and their sources
MarketWhat is checked
European Union

Regulation (EC) 1333/2008, Annex II Part B, version , contains the exact code E302: Calcium ascorbate.

Listing alone does not allow every food use. Part E food categories, limits, specifications and applicable later acts still need a product-specific check. Source read: .

Great Britain

The FSA register record for E302 (Calcium ascorbate) lists “Authorised” in England, Scotland and Wales.

Register updated: 01 April 2025; record checked: . Food-specific conditions and specifications still need a separate legal check.

United States

Selected US conditions for Calcium ascorbate

Official federal text current through ; read .

Food uses, limits and exceptions

A named GRAS provision

Calcium ascorbate is listed for use under good manufacturing practice. This means food-grade material and an amount no greater than reasonably needed for its intended effect; it does not mean unlimited use.

21 CFR 182.3189 · 21 CFR 182.1

EatMatrix’s reading: a legal use condition answers where and how an ingredient may be used. It is not a test of your product, a personal safe intake or a claim that the ingredient benefits your body. Match the named substance, food and amount. Other federal provisions, food standards, state rules and later changes may also apply; this is a selected source review, not a complete product-compliance decision.

Northern Ireland

Review pending. Check the applicable EU rules and territory arrangements; the GB register alone does not establish this status. FSA guidance is a starting source, not a verified permission for this entry.

Canada

Named food-use records located. Health Canada lists the preparations below for specified foods and purposes. This is conditional permission for those uses, not approval of every product or a personal safety verdict.

Only the named records and conditions below were located. Exact composition and specifications still need matching.

Source tables captured . List publication dates are shown separately. Good Manufacturing Practice (GMP) is a condition of use, not an unlimited amount or a recommended intake.

Food and Drug Regulations B.16.003 requires the listed source, purpose, amount and other conditions to match. The official consolidation read was current to 21 September 2026; product specifications and applicable later changes still need checking.

Read 7 listed food-use conditions

Calcium Ascorbate

Health Canada: List of Permitted Preservatives. List published ; item C.1.

  • Food: (a) Beer; Cider; Fruit wine; Wine

    Purpose: (a) Preservative

    Limit and conditions: (a) Good Manufacturing Practice

  • Food: (b) Canned applesauce

    Purpose: (b) Preservative

    Limit and conditions: (b) If used singly, the amount not to exceed 150 ppm, calculated as ascorbic acid. If used in combination with erythorbic acid or sodium erythorbate, or both, the total combined amount not to exceed 150 ppm, calculated as ascorbic acid and erythorbic acid, respectively.

  • Food: (c) Canned mandarin oranges

    Purpose: (c) Preservative

    Limit and conditions: (c) 400 ppm, calculated as ascorbic acid

  • Food: (d) Canned mushrooms; Canned white asparagus; Frozen (naming the fruit or fruits)

    Purpose: (d) Preservative

    Limit and conditions: (d) Good Manufacturing Practice

  • Food: (e) Canned peaches

    Purpose: (e) Preservative

    Limit and conditions: (e) 550 ppm, calculated as ascorbic acid

  • Food: (f) Canned tuna; Frozen minced fish; Glaze for frozen fish; Headcheese; Meat binder sold for use in preserved meat or preserved meat by-product; Preserved fish or preserved meat (as defined in section B.21.002 of the Food and Drug Regulations ); Preserved meat or preserved meat by-product; Preserved poultry meat or preserved poultry meat by-product; Pumping pickle, cover pickle or dry cure used in the curing of preserved meat or preserved meat by-product

    Purpose: (f) Preservative

    Limit and conditions: (f) Good Manufacturing Practice

    Source modification reference: NOM/ADM-0122 (see the official list).

  • Food: (g) Unstandardized foods

    Purpose: (g) Preservative

    Limit and conditions: (g) Good Manufacturing practice

EatMatrix reading: match the exact preparation and food first. A manufacturing limit is not an acceptable daily intake (ADI). A label without the amount cannot establish exposure, and an unlisted name here does not establish a ban.

Australia

Review pending. Food Standards Code permissions and conditions need an additive-specific check. FSANZ food-additive rules is a starting source, not a verified permission for this entry.

New Zealand

Review pending. Food Standards Code permissions and conditions need an additive-specific check. FSANZ food-additive rules is a starting source, not a verified permission for this entry.

Japan

Review pending. The relevant list, identity and use standards need an additive-specific check. CAA food-additive lists is a starting source, not a verified permission for this entry.

Sources & review status

Check what each source covers: an authority’s conclusion, a research finding and a country’s legal permission answer different questions.

What this guide covers

Selected research
1 source summaries, with publication dates and study types. Several publications may describe the same study population.
Official assessment sources
Commission-listed EFSA references for E302. Bibliographic identity checked; latest findings and current use rules need separate review.
Original ingredient record
1 research link; newest recorded date: . Sources added separately to this guide are not included in this count.

This guide brings together our ingredient record and the dated sources shown here. Missing information describes a gap in this guide; it does not mean an ingredient is untested, safe or harmful. This is not a complete review of every study, preparation or current country rule. The amount in a product and how it is used still matter.

How to read the ratings, research and country checks
Agency labels recorded by EatMatrix

These are imported database classifications, not verified current statements from each authority. Use the dated official sources below for their actual scope and conclusions.

AuthorityDatabase label
FDASafe
WHOSafe
EFSASafe
FSANZSafe
JapanSafe
UK FSASafe
Health CanadaSafe

Official assessment sources for E302

The European Commission’s re-evaluation table lists official EFSA documents for this additive. Their identifiers and subjects were checked against publisher bibliographic records. A missing research link in the EatMatrix database does not mean the additive has never been assessed.

Name in the Commission table: Calcium ascorbate.

These are assessment references, including historical or group assessments. They do not establish the latest scientific conclusion, a human health benefit or risk, or current permission to use the additive in a particular food. Later assessments, corrections and food-use conditions need separate review. The recorded EatMatrix rating above is unchanged.

European Commission re-evaluation table, status as of . EatMatrix checked this bibliography on .

Database updated: . What does an E number mean on a food label?

Common questions

Frequently asked questions

What is EatMatrix's recorded rating for E302?

The recorded EatMatrix rating for E302 (Calcium ascorbate) is “Safe”. It is calculated from labels stored in our ingredient database. These labels are not verified current regulator decisions or country permissions. A database update date is not a scientific review date.

Is E302 vegan, halal or gluten-free?

According to our ingredient data for Calcium ascorbate — vegan: yes, vegetarian: yes, halal: yes, kosher: yes, gluten-free: yes, dairy-free: yes. Manufacturing sources can vary between products; check the label if it matters to you.

What is E302 and why is it used?

Calcium ascorbate (E302) is a buffered, less acidic form of vitamin C made by combining ascorbic acid with calcium. It is used in food as an antioxidant to preserve color and flavor, and as a dietary supplement that is gentler on the stomach than plain vitamin C while also contributing a small amount of calcium. It supports the same immune and antioxidant functions as other forms of vitamin C.

Does E302 contain allergens?

No known allergens are recorded for Calcium ascorbate.

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This page shows information and classifications recorded in our ingredient database. Current scientific and market-specific verification remains pending as described above. It is general information, not medical advice.